Os(VIII) | An-Najah Staff

Osmium(VIII)-Catalyzed Oxidation of Some Cyclic Amines by Potassium Hexacyanoferrate(III) in Alkaline Media: a Kinetics and Mechanistic Study

Wed, 2014-04-02 12:27 — Dr. Waheed J. Jondi

Journal Title, Volume, Page:

Chemistry of Heterocyclic Compounds, Volume 39, Issue 4, pp 478-484

Year of Publication:

2003

Link:

http://link.springer.com/article/10.1023%2FA%3A1024765330259

Authors:

W. J. Jondi

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

A. A. Amer

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

M. M. Al-Subu

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

M. Hannoun

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

M. J. Musmar

College of Pharmacy, An-Najah National University, Nablus, Palestine

Preferred Abstract (Original):

Reactions of morpholine, piperidine, and piperazine with Os(VIII)-catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength. The reactions followed first-order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)6 3-] and [OH-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity, and temperature have also been studied. A mechanism accounting for these results has been proposed.

Osmium(VIII)-Catalyzed Oxidation of Some Cyclic Amines by Potassium Hexacyanoferrate(III) in Alkaline Media: a Kinetics and Mechanistic Study

Mon, 2014-02-03 10:36 — Mohammad Musmar

Journal Title, Volume, Page:

Chemistry of Heterocyclic Compounds April 2003, Volume 39, Issue 4, pp 478-484

Year of Publication:

2003

Link:

http://link.springer.com/article/10.1023%2FA%3A1024765330259

Authors:

M. M. Al-Subu

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

W. J. Jondi

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

A. A. Amer

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

M. Hannoun

Department of Pharmacy, Faculty of Medicine and Health Sciences, An-Najah National University, Nablus, Palestine

M. J. Musmar

Department of Pharmacy, Faculty of Medicine and Health Sciences, An-Najah National University, Nablus, Palestine

Current Affiliation:

Department of Pharmacy, Faculty of Medicine and Health Sciences, An-Najah National University, Nablus, Palestine

[email protected]

Preferred Abstract (Original):

Reactions of morpholine, piperidine, and piperazine with Os(VIII)-catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength. The reactions followed first-order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)₆ ^3-] and [OH^-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity, and temperature have also been studied. A mechanism accounting for these results has been proposed.

Osmium(VIII)-Catalyzed Oxidation of Some Cyclic Amines by Potassium Hexacyanoferrate(III) in Alkaline Media: a Kinetics and Mechanistic Study

Sun, 2014-01-05 14:40 — Mohammed Al-Subu'

Journal Title, Volume, Page:

Chemistry of Heterocyclic Compounds April 2003, Volume 39, Issue 4, pp 478-484

Year of Publication:

2003

Link:

http://link.springer.com/article/10.1023/A%3A1024765330259

Authors:

M. M. Al-Subu

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

W. J. Jondi

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

A. A. Amer

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

M. Hannoun

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

M. J. Musmar

Department of Pharmacy, Faculty of Medicine and Health Sciences, An-Najah National University, Nablus, Palestine

Preferred Abstract (Original):

Reactions of morpholine, piperidine, and piperazine with Os(VIII)-catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength. The reactions followed first-order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)₆ ^3-] and [OH^-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity, and temperature have also been studied. A mechanism accounting for these results has been proposed.