Electrochemical system

warad's picture

Evaluation of Pelargonium extract and oil as eco-friendly corrosion inhibitor for steel in acidic chloride solutions and pharmacological properties

Journal Title, Volume, Page: 
Research on Chemical Intermediates September 2014 Date: 28 Sep 2014
Year of Publication: 
2014
Authors: 
Y. El Ouadi
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
L. Majidi
Laboratoire des Substances Naturelles & Synthese et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco
A. Bouyanzer
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
J. Paolini
Laboratoire des Substances Naturelles & Synthese et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco
J.-M. Desjobert
J. Costa
A. Chetouani
B. Hammouti
S. Jodeh
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
I. Warad
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Y. Mabkhot
T. Ben Hadda
Preferred Abstract (Original): 

There is a growing trend in utilizing plant extracts and pharmaceutical compounds as corrosion inhibitors. Accurate identification of the essential oil of aerial parts of Pelargonium was obtained using hydrodistillation, gas chromatography and gas chromatography–mass spectrometry. The oil was predominated by citronellol (22.8 %). The inhibitory effect of essential oil and extract of Pelargonium was estimated on the corrosion of mild steel in 1 M hydrochloric acid (HCl) using weight loss, electrochemical impedance spectroscopy (EIS) and Tafel polarization curves. Inhibition was found to increase with increasing concentration of the essential oil and extract of Pelargonium. The effect of temperature on the corrosion behavior of mild steel in 1 M HCl with addition of essential oil and extract was also studied, and the thermodynamic parameters were determined and discussed. Values of inhibition efficiency were calculated from weight loss, Tafel polarization curves, and EIS. All results are in good agreement. Polarization curves showed that essential oil and extract of Pelargonium behave as mixed type inhibitors in HCl (1 M). The results obtained showed that the essential oil and extract of Pelargonium could serve as an effective inhibitor of the corrosion of mild steel in HCl solution. To avoid any unexpected toxicity, the majority of compounds have been studied by using POM analyses. 

sjodeh's picture

Evaluation of Pelargonium Extract and Oil as Eco-Friendly Corrosion Inhibitor for Steel in Acidic Chloride Solutions and Pharmacological Properties

Journal Title, Volume, Page: 
Research on Chemical Intermediates September 2014 Date: 28 Sep 2014
Year of Publication: 
2014
Authors: 
Y. El Ouadi
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
A. Bouyanzer
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
L. Majidi
Laboratoire des Substances Naturelles & Synthese et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco
J. Paolini
UMR CNRS 6134, Laboratoire de Chimie des Produits Naturels, Faculté des Sciences et Techniques, Université de Corse, Corsica, France
J.-M. Desjobert
UMR CNRS 6134, Laboratoire de Chimie des Produits Naturels, Faculté des Sciences et Techniques, Université de Corse, Corsica, France
J. Costa
UMR CNRS 6134, Laboratoire de Chimie des Produits Naturels, Faculté des Sciences et Techniques, Université de Corse, Corsica, France
A. Chetouani
Laboratoire de chimie physique, Centre Régionale des Métiers de l’Education et de Formation “CRMEF”, Région de l’Orientale, Oujda, Morocco
B. Hammouti
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
S. Jodeh
Department of Chemistry, AN-Najah National University, P. O. Box 7, Nablus, State of Palestine
Current Affiliation: 
Department of Chemistry, AN-Najah National University, P. O. Box 7, Nablus, State of Palestine
I. Warad
Department of Chemistry, AN-Najah National University, P. O. Box 7, Nablus, State of Palestine
Y. Mabkhot
Department of Chemistry, College of Science, King Saud University, P. O. Box 2455, Riyadh, 11451, KSA
T. Ben Hadda
Laboratoire Chimie Matériaux, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
Preferred Abstract (Original): 

There is a growing trend in utilizing plant extracts and pharmaceutical compounds as corrosion inhibitors. Accurate identification of the essential oil of aerial parts of Pelargonium was obtained using hydrodistillation, gas chromatography and gas chromatography–mass spectrometry. The oil was predominated by citronellol (22.8 %). The inhibitory effect of essential oil and extract of Pelargonium was estimated on the corrosion of mild steel in 1 M hydrochloric acid (HCl) using weight loss, electrochemical impedance spectroscopy (EIS) and Tafel polarization curves. Inhibition was found to increase with increasing concentration of the essential oil and extract of Pelargonium. The effect of temperature on the corrosion behavior of mild steel in 1 M HCl with addition of essential oil and extract was also studied, and the thermodynamic parameters were determined and discussed. Values of inhibition efficiency were calculated from weight loss, Tafel polarization curves, and EIS. All results are in good agreement. Polarization curves showed that essential oil and extract of Pelargonium behave as mixed type inhibitors in HCl (1 M). The results obtained showed that the essential oil and extract of Pelargonium could serve as an effective inhibitor of the corrosion of mild steel in HCl solution. To avoid any unexpected toxicity, the majority of compounds have been studied by using POM analyses.

warad's picture

Evaluation of Pelargonium Extract and Oil as Eco-Friendly Corrosion Inhibitor for Steel in Acidic Chloride Solutions and Pharmacological Properties

Journal Title, Volume, Page: 
Research on Chemical Intermediates September 2014 Date: 28 Sep 2014
Year of Publication: 
2014
Authors: 
Y. El Ouadi
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
A. Bouyanzer
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
L. Majidi
Laboratoire des Substances Naturelles & Synthese et Dynamique Moléculaire, Faculté des Sciences et Techniques, Errachidia, Morocco
J. Paolini
UMR CNRS 6134, Laboratoire de Chimie des Produits Naturels, Faculté des Sciences et Techniques, Université de Corse, Corsica, France
J.-M. Desjobert
UMR CNRS 6134, Laboratoire de Chimie des Produits Naturels, Faculté des Sciences et Techniques, Université de Corse, Corsica, France
J. Costa
UMR CNRS 6134, Laboratoire de Chimie des Produits Naturels, Faculté des Sciences et Techniques, Université de Corse, Corsica, France
A. Chetouani
Laboratoire de chimie physique, Centre Régionale des Métiers de l’Education et de Formation “CRMEF”, Région de l’Orientale, Oujda, Morocco
B. Hammouti
Laboratoire de Chimie Appliquée et Environnement (LCAE), URAC18, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
S. Jodeh
Department of Chemistry, AN-Najah National University, P. O. Box 7, Nablus, State of Palestine
I. Warad
Department of Chemistry, AN-Najah National University, P. O. Box 7, Nablus, State of Palestine
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Y. Mabkhot
Department of Chemistry, College of Science, King Saud University, P. O. Box 2455, Riyadh, 11451, KSA
T. Ben Hadda
Laboratoire Chimie Matériaux, Faculté des Sciences, B.P. 717, 60000, Oujda, Morocco
Preferred Abstract (Original): 
There is a growing trend in utilizing plant extracts and pharmaceutical compounds as corrosion inhibitors. Accurate identification of the essential oil of aerial parts of Pelargonium was obtained using hydrodistillation, gas chromatography and gas chromatography–mass spectrometry. The oil was predominated by citronellol (22.8 %). The inhibitory effect of essential oil and extract of Pelargonium was estimated on the corrosion of mild steel in 1 M hydrochloric acid (HCl) using weight loss, electrochemical impedance spectroscopy (EIS) and Tafel polarization curves. Inhibition was found to increase with increasing concentration of the essential oil and extract of Pelargonium. The effect of temperature on the corrosion behavior of mild steel in 1 M HCl with addition of essential oil and extract was also studied, and the thermodynamic parameters were determined and discussed. Values of inhibition efficiency were calculated from weight loss, Tafel polarization curves, and EIS. All results are in good agreement. Polarization curves showed that essential oil and extract of Pelargonium behave as mixed type inhibitors in HCl (1 M). The results obtained showed that the essential oil and extract of Pelargonium could serve as an effective inhibitor of the corrosion of mild steel in HCl solution. To avoid any unexpected toxicity, the majority of compounds have been studied by using POM analyses.
Syndicate content