Uptake of cadmium from aqueous solutions by beech leaves has been studied. The effect of several factors on both rate and amount of this uptake has been studied. These factors include concentration of leaves, concentration of cadmium, pH, competing ions and drying leaves. The pattern of the curves showing the loss of cadmium from solution has been explained. Applicability of the Freündlich adsorption isotherm on the present results has been examined and the parameters of this isotherm have been calculated. The order of reaction between cadmium ions and beech leaves has been determined and a mechanism for this reaction has been suggested.
Decaying leaves have been proven capable of partially removing lead
from polluted water. Several factors affecting the removal process have
been studied. These include the concentration of lead ions,
concentration of leaves, drying leaves, degree of crushing of leaves,
leaf extracts, pH, agitation and presence of competing and of complexing
agents. The relative capability of some common types of leaves for the
removal of lead from water has been studied.
The release of lead
from leaves saturated with lead ions has been studied under the effect
of varying pH, addition of competing ions and the addition of complexing
agents.
The results of the present work indicate
that the interaction between lead ions and leaves is mainly an
adsorption process and fit the Freundlich adsorption isotherm whose
parameters have also been calculated. A fractional order of reaction
(0.7) has been determined for the reaction between lead ions and leaves
using two methods of evaluation. A mechanism in which film diffusion
being the most probable limiting step has been suggested.