Cd(II) complexes, | An-Najah Staff

(2,9-Dimethyl-1,10-Phenanthroline-π 2N,N')Diiodidocadmium

Wed, 2013-03-13 16:42 — Ismail Warad

Journal Title, Volume, Page:

Acta Cryst. (2011), Volume 67,Part 12, Page m1650 [doi:10.1107/S1600536811044667]

Year of Publication:

2011

Link:

http://journals.iucr.org/e/issues/2011/12/00/pk2353/index.html

Authors:

Ismail Warad

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Ahmed Boshaala

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Saud I. Al-Resayes

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Salem S. Al-Deyab

Petrochemical Research Chair, College of Science, King Saud, University, Riyadh, Saudi Arabia

Mohamed Rzaiguic

Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia

[email protected]

Preferred Abstract (Original):

In the title compound, [CdI2(C14H12N2)], the molecule sits on a crystallographic twofold axis. The coordination sphere of the CdII atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetrahedral geometry. Inversion-related molecules interact along the c-axis direction by π -π stacking interactions between the phenanthroline ring systems, with centroid-centroid distances of 3.707 (9) and 3.597 (10) Å.

Dibromido(2,9-Dimethyl-1,10-Phenanthroline- 2N,N')Cadmium

Wed, 2013-03-13 16:33 — Ismail Warad

Journal Title, Volume, Page:

Acta Crystallographica Section E, Volume 67, Part 12, Pages m1846-m1847, December 2011

Year of Publication:

2011

Link:

http://journals.iucr.org/e/issues/2011/12/00/hb6522/index.html

Authors:

Ismail Warad

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Ahmed Boshaala

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Saud I. Al-Resayes

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Salem S. Al-Deyab

Petrochemical Research Chair, College of Science, King Saud University, Riyadh, Saudi Arabia

Mohamed Rzaigui

Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia

[email protected]

Preferred Abstract (Original):

In the title complex, [CdBr2(C14H12N2)], the CdII ion is tetracoordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substantially distorted CdN2Br2 tetrahedral geometry. In the crystal, inversion dimers linked by pairs of weak C-H Br bonds generate R22(14) loops. Aromatic - stacking [shortest centroid-centroid separation = 3.633 (2) Å] interactions occur within, and also link, the dimers into chains propagating parallel to [100].

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)cadmium

Sun, 2012-12-16 15:01 — Ismail Warad

Journal Title, Volume, Page:

Acta Crystallogr Sect E Struct Rep Online. 2011 December 1; 67(Pt 12): m1846–m1847

Year of Publication:

2011

Link:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238742/

Authors:

Ismail Warad

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Ahmed Boshaala

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Saud I. Al-Resayes

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Salem S. Al-Deyab

Petrochemical Research Chair, College of Science, King Saud University, Riyadh, Saudi Arabia

Mohamed Rzaigu

Laboratoire de Chimie des Materiaux, Faculte des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia Correspondence

[email protected]

Preferred Abstract (Original):

In the title complex, [CdBr2(C14H12N2)], the CdII ion is tetra¬coordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substanti¬ally distorted CdN2Br2 tetra¬hedral geometry. In the crystal, inversion dimers linked by pairs of weak C—H Br bonds generate R 2 2(14) loops. Aromatic π–π stacking [shortest centroid–centroid separation = 3.633 (2) Å] inter¬actions occur within, and also link, the dimers into chains propagating parallel to [100].