Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)cadmium

Journal Title, Volume, Page:

Acta Crystallogr Sect E Struct Rep Online. 2011 December 1; 67(Pt 12): m1846–m1847

Year of Publication:

2011

Link:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238742/

Authors:

Ismail Warad

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Ahmed Boshaala

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Saud I. Al-Resayes

Department of Chemistry, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Salem S. Al-Deyab

Petrochemical Research Chair, College of Science, King Saud University, Riyadh, Saudi Arabia

Mohamed Rzaigu

Laboratoire de Chimie des Materiaux, Faculte des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia Correspondence

[email protected]

Preferred Abstract (Original):

In the title complex, [CdBr2(C14H12N2)], the CdII ion is tetra¬coordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substanti¬ally distorted CdN2Br2 tetra¬hedral geometry. In the crystal, inversion dimers linked by pairs of weak C—H Br bonds generate R 2 2(14) loops. Aromatic π–π stacking [shortest centroid–centroid separation = 3.633 (2) Å] inter¬actions occur within, and also link, the dimers into chains propagating parallel to [100].

Attachment	Size
Dibromido_(2_9_dimethyl_110_phenanthroline_κ2_N,N)Cadmium.pdf	864.06 KB

An-Najah Staff

Author Information

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)cadmium