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Hemilabile ether-phosphine

Mohammed Suleiman Shtaya's picture

Synthesis, Identification and NMR of New Transdichloro- piperazine bis(ether-phosphine)ruthenium(II) Complex

Thu, 2015-02-05 15:18 — Mohammed Suleiman Shtaya
Journal Title, Volume, Page: 
Suleiman & al. / Mor. J. Chem. 1 N°2 (2013) 29-32
Year of Publication: 
2013
Link: 
http://revues.imist.ma/?journal=morjchem&page=article&op=view&path%5B%5D=1933
Authors: 
Mohammed Suleiman
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
[email protected]
Mousa Al-Noaimi
Department of Chemistry, Hashemite University, Zarqa 13115, Jorda
Belkheir Hammouti
LCAE-URAC18, Faculty of Science, University Mohammed Premier, Oujda-60000, Morocco
Smaail Radi
LCAE-URAC18, Faculty of Science, University Mohammed Premier, Oujda-60000, Morocco
Taibi Ben Hadda
Laboratoire Chemie Materiaux, FSO, Université Mohammed Premier, Oujda-60000, Morocco
Ahmed Boshaala
Department of Chemistry, Faculty of Science, Benghazi University P. O. Box 1308 Benghazi, Libya
Ismail Warad
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Preferred Abstract (Original): 

1-hTrans-dichloro-piperazine-bis(ether-phosphine)ruthenium(II) complex of general formula Cl2Ru(Ph2PCH2CH2OCH3)2(C4H10N2) 2 was made available in good yield through treating equimolar amounts of O)2 complex 1 with piperazine as co-ligand. The hemilability ring open reaction of ether-phosphine inÇCl2Ru(Pcomplex 1 to prepare complex 2 was monitored by 31P-NMR. The structure of complex 2 was confirmed by elemental analysis, IR, 31P-NMR 1H-NMR,13C-NMR, FAB-MS and UV-visible spectroscopy.

warad's picture

Synthesis, Identification and NMR of New Trans-dichloro-piperazine bis(ether-phosphine)ruthenium(II) Complex

Thu, 2014-06-12 21:57 — Ismail Warad
Year of Publication: 
2013
Link: 
http://revues.imist.ma/?journal=morjchem&page=article&op=view&path%5B%5D=1933
Preferred Abstract (Original): 
Trans-dichloro-piperazine-bis(ether-phosphine)ruthenium(II) complex of general  formula Cl2Ru(h1-Ph2PCH2CH2OCH3)2(C4H10N2) 2 was made available in good yield through treating equimolar amounts of Cl2Ru(PÇO)2 complex 1 with piperazine as co-ligand. The hemilability ring open reaction of ether-phosphine in complex 1 to prepare complex 2 was monitored by 31P-NMR. The structure of complex 2 was confirmed byelemental analysis, IR, 31P-NMR 1H-NMR,13C-NMR, FAB-MS and UV-visible spectroscopy.
warad's picture

Trans-Dichloro-2,3-Naphthalenediamine Bis[(2-Methoxyethyl)(Diphenyl)Phosphine]-Ruthenium(II) Complex

Thu, 2013-03-14 17:02 — Ismail Warad
Journal Title, Volume, Page: 
Molbank 2010, 2010(3), M696; doi:10.3390/M696
Year of Publication: 
2010
Link: 
http://www.mdpi.com/1422-8599/2010/3/M696
Authors: 
Ismail Warad
Department of Chemistry, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia; E-Mail: [email protected]; Tel./Fax: +96-61-4675992
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
[email protected]
Preferred Abstract (Original): 
Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)¬(diphenyl)¬phos¬phine]¬¬ruthenium(II) complex Cl2Ru(h1-Ph2PCH2CH2OCH3)2(C10H10N2) has been obtained by reaction of equimolar amounts of Cl2Ru(PÇO)2 complex 2 with one equivalent of 2,3-naphthalenediamine as co-ligand in very good yield. The structure of this new complex 3 was confirmed by elemental analysis, IR, 31P-NMR 1H-NMR, 13C-NMR, UV-visible spectroscopy and FAB-MS.
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