An-Najah Staff

Background: Photo-degradation of organic contaminants into non-hazardous mineral compounds is emerging as

a strategy to purify water and environment. Tremendous research is being done using direct solar light for these

purposes. In this paper we report on optimum conditions for complete mineralization of aqueous methyl orange

using lab-prepared ZnO nanopowder catalyst under simulated solar light.

Results: Nano-scale ZnO powder was prepared in the lab by standard methods, and then characterized using electronic

absorption spectra, photolumenscence emission (PL) spectra, XRD, and SEM. The powder involved a wurtzite structure

with ~19 nm particles living in agglomerates. Photo-degradation progressed faster under neutral or slightly acidic

conditions which resemble natural waters. Increasing catalyst concentration increased photodegradation rate to a certain

limit. Values of catalyst turn over number and degradation percentage increased under higher light intensity, whereas the

quantum yield values decreased. The photocatalytic efficiency of nano-ZnO powders in methyl orange photodegradation

in water with solar light has been affected by changing the working conditions. More importantly, the process may be

used under natural water conditions with pH normally less than 7, with no need to use high concentrations of catalyst or

contaminant. The results also highlight the negative impact of possible high concentrations of CO2 on water purification

processes. Effects of other added gaseous flows to the reaction mixture are also discussed.

Conclusion: ZnO nano-particles are useful catalyst for complete mineralization of organic contaminants in water.

Photo-degradation of organic contaminants with ZnO nano-particles, methyl orange being an example, should

be considered for future large scale water purification processes under natural conditions

Nano-scale ZnO powder was prepared in the lab by standard methods, and then characterized

using electronic absorption spectra, photolumenscence emission (PL) spectra, XRD, and

SEM. The powder involved a wurtzite structure with ~19 nm particles living in agglomerates.

Photo-degradation progressed faster under neutral or slightly acidic conditions which

resemble natural waters. Increasing catalyst concentration increased photodegradation rate to

a certain limit. Values of catalyst turn over number and degradation percentage increased

under higher light intensity, whereas the quantum yield values decreased. The photocatalytic

efficiency of nano-ZnO powders in methyl orange photodegradation in water with solar light

has been affected by changing the working conditions. More importantly, the process may be

used under natural water conditions with pH normally less than 7, with no need to use high

concentrations of catalyst or contaminant. The results also highlight the negative impact of

possible high concentrations of CO

 on water purification processes. Effects of other added

gaseous flows to the reaction mixture are also discussed.

ZnO nano-particles are useful catalyst for complete mineralization of organic contaminants in

water. Photo-degradation of organic contaminants with ZnO nano-particles, methyl orange

being an example, should be considered for future large scale water purification processes

under natural conditions.