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Cd(II) complexes; DPMNPH ligand; X-ray single crystal structure; Intramolecualar hydrogen bonding

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Structural studies on Cd(II) complexes incorporating di-2-pyridyl ligand and the X-ray crystal structure of the chloroform solvated DPMNPH/CdI2 complex

Fri, 2014-03-14 23:12 — Ismail Warad
Journal Title, Volume, Page: 
Inorganic Chemistry Communications inpress
Year of Publication: 
2014
Link: 
http://www.sciencedirect.com/science/article/pii/S1387700314000926
Preferred Abstract (Original): 
A series of novel Cd(II) complexes incorporating ligand, di(2-pyridinyl)methanone N-(2-
pyridinyl)hydrazone (DPMNPH), has been investigated. The ligand, DPMNPH, and its
corresponding complexes have been characterized with the help of number of techniques:
microanalysis, FT-IR, 1H-and 13C-NMR, UV/Vis spectroscopy, thermal studies and MSFAB
mass spectrometry. In addition, single crystal X-ray diffrction measurement studies
are also employed in one of the complexes showing a distorted trigonal bipyramidal
geometry. Furthermore, the existence of NH....Npy intramolecular hydrogen bonding
interactions in the ligand and its corresponding complexes have also been reported.
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