Trans-Dichlorido (2,2-Dimethylpropane-1,3-Diamine) Bis(Triphenylphosphane) Ruthenium(II)

Journal Title, Volume, Page:

Acta Crystallographica Section E, Volume 66, Part 7, Pages m731-m732, July 2010

Year of Publication:

2010

Link:

http://journals.iucr.org/e/issues/2010/07/00/tk2679/index.html

Authors:

Monther A. Khanfar

Department of Chemistry, The University of Jordan, Amman 11942, Jordan

[email protected]

Ismail Warad

Department of Chemistry, King Saud University, PO Box 2455, Riyadh-11451, Saudi Arabia

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Murad A. AlDamen

Department of Chemistry, The University of Jordan, Amman 11942, Jordan

Preferred Abstract (Original):

In the title compound, [RuCl2(C5H14N2)(C18H15P)2], the RuII atom is six-coordinated, forming a slightly distorted octahedral geometry, with two chloride ions in an axial arrangement, and two P atoms of two triphenylphosphane and two chelating N atoms of the bidentate 2,2-dimethylpropane-1,3-diamine ligand located in the equatorial plane. The average Ru-P, Ru-N and Ru-Cl bond lengths are 2.325 (18), 2.1845 (7) and 2.4123 (12) Å, respectively.

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Trans-Dichlorido (2,2-Dimethylpropane-1,3-Diamine) Bis(Triphenylphosphane) Ruthenium(II)