Synthesis, Spectral And Structural Charcterization Of Novel Dichloro-Ruthenium(II)/Triphenylphosphine/(3,4-Diaminophenyl)(Phenyl)Methanone Complex

Journal Title, Volume, Page:

J. Mater. Environ. Sci. 4(5) (2013) 822-827

Year of Publication:

2013

Link:

http://www.jmaterenvironsci.com/Document/vol4/vol4_N5/111-JMES-489bis-2013-Warad...

Authors:

Ismail Warad

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Preferred Abstract (Original):

The novel trans-[Cl2Ru(II)(PPh3)2(3,4-diaminophenyl)(phenyl)methanone] complex was obtained by reacting RuCl2(PPh3)3 with equimolar amounts of (3,4-diaminophenyl)(phenyl)methanone as diamine co-ligand in CH2Cl2. One of the PPh3 ligand was quantitatively exchanged by (3,4-diaminophenyl)(phenyl)methanone, even when excess diamine was added. The trans-RuCl2 desired complex was characterized on the basis of elemental analysis, elemental analysis, FAB-MS, IR, UV-vis, 1H, 13C and 31P{1H}NMR.

An-Najah Staff

Author Information

Synthesis, Spectral And Structural Charcterization Of Novel Dichloro-Ruthenium(II)/Triphenylphosphine/(3,4-Diaminophenyl)(Phenyl)Methanone Complex