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Cis-[1,4-Bis(Diphenyl­Phosphan­Yl)Butane-Κ2 P,P′]Dichlorido(Cyclo­Hexane-1,2-Diamine-Κ2 N,N′)Ruthenium(II) Dichloro­Methane MonosolvateIn the title compound, [RuCl2(C6H14N2)(C28H28P2)]•CH2Cl2, the RuII ion is coordinated in a slightly distorted octa¬hedra

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Mon, 2014-10-20 10:08 — Ismail Warad
Journal Title, Volume, Page: 
Acta Cryst. (2012). E68, m563-m564 [ doi:10.1107/S1600536812014080]
Year of Publication: 
2012
Link: 
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344316/#__ffn_sectitle
Authors: 
Ismail Warad
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
[email protected]
Preferred Abstract (Original): 

In the title compound, [RuCl2(C6H14N2)(C28H28P2)]·CH2Cl2, the RuII ion is coordinated in a slightly distorted octa­hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis­(diphenyl­phosphan­yl)butane ligand and two cis-chelating N atoms of a bidentate cyclo­hexane-1,2-diamine ligand. In the crystal, pairs of mol­ecules form inversion dimers via N—H(...)Cl hydrogen bonds. In addition, intra­molecular N—H(...)Cl and weak C—H(...)Cl, C—H(...)N, N—H(...)π and C—H(...)π hydrogen bonds are observed. One of the Cl atoms of the solvent mol­ecule is disordered over two sites with refined occupancies of 0.62 (1) and 0.38 (1).

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Cis-[1,4-Bis(Diphenyl­Phosphan­Yl)Butane-Κ2_P,P′]Dichlorido(Cyclo­Hexane-1,2-Diamine-Κ2_N,N′)Ruthenium(II)_Dichloro­Methane_MonosolvateIn_the_title_compound,_[RuCl2(C6H14N2)(C28H28P2)]•CH2Cl2,_the_RuII_ion_is_coordinated_in_a_slig.pdf500.15 KB