[1,2-Bis(Diphenylphosphanyl)Ethane- 2P,P']Dichloridopalladium(II) Dimethyl Sulfoxide Monosolvate

Journal Title, Volume, Page:

Acta Crystallographica Section E, Volume 68, Part 7

Year of Publication:

2012

Link:

http://journals.iucr.org/e/issues/2012/07/00/hb6864/index.html

Authors:

Ismail Warad

Department of Chemistry, College of Science, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Abdullah S. Aldwayyan

Department of Physics and Astronomy, College of Science, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia

Fahad M. Al-Jekhedab

Electronics, Communications and Photonics Program, King Abdulaziz City for Science and Technology, PO Box 6086, Riyadh 11442, Saudi Arabia

M. Iqbal Choudhary

H.E.J. Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi, Karachi 75270, Pakistan

Sammer Yousuf

H.E.J. Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi, Karachi 75270, Pakistan

[email protected]

Preferred Abstract (Original):

In the title compound, [PdCl2(C26H24P2)].C2H6OS, the PdII atom adopts a distorted cis-PdCl2P2 square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methylene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent molecule are disordered over two sets of sites in a 0.8976 (18):0.1024 (18) ratio. The DMSO O atom accepts three C-H O hydrogen bonds from an adjacent complex molecule.

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[1,2-Bis(Diphenylphosphanyl)Ethane- 2P,P']Dichloridopalladium(II) Dimethyl Sulfoxide Monosolvate