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SN Ar Displacement of Fluorine From Pentafluoropyridin by Sodium Oximates: Unprecedented ‎Substitution Patterns

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Tue, 2014-04-01 11:25 — Dr. Waheed J. Jondi
Journal Title, Volume, Page: 
Journal of the Chemical Society, Chemical Communications, Issue 17
Year of Publication: 
1989
Link: 
http://pubs.rsc.org/en/content/articlelanding/1989/c3/c39890001268
Authors: 
Waheed Jondi
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
[email protected]
Ronald Eric Banks
Anthony Edgar Tipping
Preferred Abstract (Original): 

Displacement of fluorine from pentafluoropyridine under conditions by sodium oximates RR′C[double bond, length as m-dash]NO–Na+[R,R′= Me or Ph; R = Me, R′= Ph (anti isomer)] suspended in benzene or diethyl ether yields O-tetrafluoropyridyl oximes arising from monosubstitution at both 2- and 4-positions.