Nanoparticles for Inhibition of Asphaltenes Damage: Adsorption Study and Displacement Test on Porous Media

nassar's picture
Journal Title, Volume, Page: 
American Chemical Society
Year of Publication: 
2013
Authors: 
Camilo A. Franco
Grupo de investigacio ́ n en Yacimientos de Hidrocarburos, Facultad de Minas, Universidad Nacional de Colombia Sede Medellín, Calle 59A No 63-20 Medellín, Columbia
Nashaat N. Nassar
Department of Chemical and Petroleum Engineering, University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada
Current Affiliation: 
Department of Chemical Engineering, An-Najah National University, P.O. Box 7, Nablus, Palestine
Marco A. Ruiz
Grupo de investigacio ́ n en Yacimientos de Hidrocarburos, Facultad de Minas, Universidad Nacional de Colombia Sede Medellín, Calle 59A No 63-20 Medellín, Columbia
Pedro Rafael Pereira-Almao
Department of Chemical and Petroleum Engineering, University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada
Farid B. Cortés
Grupo de investigacio ́ n en Yacimientos de Hidrocarburos, Facultad de Minas, Universidad Nacional de Colombia Sede Medellín, Calle 59A No 63-20 Medellín, Columbia
Preferred Abstract (Original): 
The deposition of asphaltenes is one of the most difficult problems to overcome in oil production and processing. The presence of asphaltenes in crude oil, and consequently, the adsorption and deposition of asphaltenes on the rock surfaces, affects the rock properties, such as porosity, permeability and wettability. This study aims at analyzing the effect of the chemical nature of twelve types of nanoparticles on asphaltenes adsorption; hence, the delay or inhibition of deposition and precipitation of asphaltenes on porous media under flow conditions at reservoir pressure and temperature were investigated. The adsorption equilibrium of asphaltenes onto nanoparticles was effectively achieved within relatively short times (approximately 2 min), which indicates the promising nature of adsorbents for delaying the agglomeration and inhibiting the precipitation and deposition of asphaltenes. The adsorption equilibrium of asphaltenes for the nanoparticles was determined using a batch method in the range 150 - 2000 mg/L. The equilibrium adsorption data were fit to both the Langmuir and Freundlich models. Additionally, in this study, the transport of nanoparticles in a porous media at a typical reservoir pressure and temperature was investigated. As a result, the use of nanoparticles allowed the system to flow successfully, which demonstrated the inhibition of precipitation and deposition and the enhanced perdurability against asphaltene damage in the porous media.
AttachmentSize
Nanoparticles_for_Inhibition_of_Asphaltenes_Damage_Adsorption_Study_and_Displacement_Test_on_Porous_Media.pdf603.96 KB