The Synthesis and Cycloaddition Reactions of 3-Azabicyclo[3.1.0]hex-2-ene 3-oxide and 3-Azabicyclo[3.2.0]hept-2-ene 3-oxide. Highly Strained Bicyclic Nitrones

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Journal Title, Volume, Page: 
Tetrahedron Letters Volume 28, Issue 3, Pages 267–270
Year of Publication: 
1987
Authors: 
Mohammed Al-Nuri
Department of Chemistry State University of New York at Buffalo Bufflo, NY 14214 U.S.A
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Joseph J Tufariello
Department of Chemistry State University of New York at Buffalo Bufflo, NY 14214 U.S.A.
Arnold S Milowsky
Department of Chemistry State University of New York at Buffalo Bufflo, NY 14214 U.S.A
Steven Goldstein
Department of Chemistry State University of New York at Buffalo Bufflo, NY 14214 U.S.A
Preferred Abstract (Original): 

The synthesis of two strained bicyclic nitrones is described. Subsequent cycloadditions demonstrated a high degree of regiochemical and stereochemical control.

Bicyclic nitrones View the MathML source and View the MathML source were synthesized and their cycloaddition reactions with alkenes were explored.

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