Home › alkhalil › Publications › Published Researches

Effects of methanol solvation on the nucleophilic reactions of thiolates with 2-substituted-2-nitropropanes

alkhalil's picture
Sun, 2015-04-05 14:13 — Suleiman Ibrahim Al-khalil
Journal Title, Volume, Page: 
Tetrahedron letters,25,4,461-464
Year of Publication: 
1984
Authors: 
Suleiman I Al-Khalil
W Russell Bowman
Preferred Abstract (Original): 

Methanol solvation prevents SRN1 substitution in the reaction of Me2C(X)NO2 with thiolates
and favours an alternative redox reaction to yield disulphide and nit.