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A Spectroscopic Study of Preferential Solvation of Fe(bipy)2(CN)2 in Binary Aqueous 2-Ethoxy Ethanol Mixtures

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Thu, 2014-03-20 14:26 — Bassem Shraydeh
Journal Title, Volume, Page: 
Spectroscopy letters, 1994, Vol. 27, No3, pp. 333-340
Year of Publication: 
1994
Link: 
http://www.tandfonline.com/doi/pdf/10.1080/00387019408000848#.UhSAAD-56xM
Authors: 
Bassem F. Shraydeh
Chemistry Department, Faculty of Science , An-Najah National University , Nablus, Palestine
Current Affiliation: 
Department of Chemistry, An-Najah National University, Nablus, Palestine
[email protected]
Subhi Salih
Chemistry Department, Faculty of Science , An-Najah National University , Nablus, Palestine
Preferred Abstract (Original): 

Preferential Solvation of bis-(2,2′-bipyridyl) biscyanoiron(II) was investigated in 2-ethoxy ethanol water binary aqueous mixtures. The treatment showed that preferential solvation by 2-ethoxy ethanol occurs. The preferential solvation constant at 298.15° K was found to be equal to (4.96 ± 0.06) and the free energy of preferential solvations ΔG has a value of 3.97° KJ mol−1