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Solvatochromism of Ternary Iron (II) Diimine Cyanide Complexes in 2-Ethyl-2-(hydroxymethyl) 1,3-Propanediol (Trimethylol Propane)

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Thu, 2014-03-20 14:05 — Bassem Shraydeh
Journal Title, Volume, Page: 
Spectroscopy Letters: An International Journal for Rapid Communication Volume 26, Issue 1, Pages 129-135
Year of Publication: 
1993
Link: 
http://www.tandfonline.com/doi/abs/10.1080/00387019308011519#.UyrdPPmSwgY
Authors: 
Bassem F. Shraydeha
Chemistry Department, Faculty of Science , An-Najah National University , Nablus, Palestine
Current Affiliation: 
Department of Chemistry, An-Najah National University, Nablus, Palestine
[email protected]
John Burgessb
Department of Chemistry , University of Leicester , Leicester, LE1 7RH, U. K.
Preferred Abstract (Original): 

The solvatochromic behaviour of bis-(2,2′-bipyridyl)-biscyanoiron (II) and 2,2′- bipyridyltetracyanoiron (II) in 2-ethyl-2-(hydroxymethyl)-1,3-propanediol has been established. The significance and sensitivities of the solvatochromic shifts of these charge-transfer bands are outlined for the two iron complexes above.