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Effect of Molybdenum Catalysis on the ‎Perborate-Bromide Reaction. Kinetics And ‎Mechanism and some Theoretical ‎Considerations

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Thu, 2014-03-20 13:31 — Bassem Shraydeh
Journal Title, Volume, Page: 
Reaction Kinetics and Catalysis Letters, Volume 48, Issue 1, pp 49-54
Year of Publication: 
1992
Link: 
http://link.springer.com/article/10.1007/BF02070066#close
Authors: 
B. F. Shraydeh
Chemistry Department, Faculty of Science , An-Najah National University , Nablus, Palestine
Current Affiliation: 
Department of Chemistry, An-Najah National University, Nablus, Palestine
[email protected]
G. Svehla
Chemistry Department, University College Cork, Ireland
Preferred Abstract (Original): 

In the presence of molybdenum, both the uncatalyzed and the catalyzed reactions proceed simultaneously. An equation for kcat was derived and the effect of temperature was described through a temperature function F(T) by the use of the Arrhenius-Eyring equation. A plausible mechanism is postulated and the theoretical background given for the analytical application of molybdenum.