Kinetics and Mechanism of Oxidation of Triallylamine by Alkaline Potassium Hexacyanoferrate(III)

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Journal Title, Volume, Page: 
Journal- Indian Chemical Society, 01/1990; 67(12):966-969
Year of Publication: 
1990
Authors: 
Mohammed Alsubu
Current Affiliation: 
Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine
Preferred Abstract (Original): 

Kinetics of the oxidation of triallylamine by hexacyanoferrate(III) in alkaline medium have been studied. The rate is independent of the concentration of Fe(CN)6(3-), while the orders in [triallylamine] and [OH-] are nearly unity and 0.33 respectively. The rate of the reaction is not retarded by added Fe(CN)6(4-) ions. The effects of ionic strength, varying cations and anions of added salts, solvent composition and temperature on the reaction rate are reported. A suitable mechanism has been proposed.