The Role of Solvent on the Kinetics and Mechanism of the Hydrolysis of Salicylidene Benzoyl Hydrazone

Journal Title, Volume, Page:

An-Najah University Journal for Research - Natural Sciences - Volume 5, Issue 1

Year of Publication:

1988

Link:

http://scholar.najah.edu/publication/journal-article/role-solvent-kinetics-and-m...

Authors:

Maher Abu-Eid

Chemistry Department, An-Najah National University, Nablus, Palestine

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

Preferred Abstract (Original):

The effect of various solvents on the kinetics and mechanism of the hydrolysis of Salicylidene Benzoyl hydrazone (SBH) has been studied at five different temperatures (17-45 C) using U.V. and visible spectrophotometry. In both protic and aprotic solvents, the hydrolysis rates follow first order kinetics. The role of solvent on the reaction rate, thermodynamic parameters and mechanism have been reported and discussed.

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The Role of Solvent on the Kinetics and Mechanism of the Hydrolysis of Salicylidene Benzoyl Hydrazone