Polymerization of 4-Methylpentene -1- by the MgCl2|Eb|TiCl4|Al(iBu)3 Catalyst System 1. Kinetic Investigations

Journal Title, Volume, Page:

An-Najah University Journal for Research - Natural Sciences - Volume 8, Issue 1

Year of Publication:

1994

Link:

http://scholar.najah.edu/publication/journal-article/polymerization-4-methylpent...

Authors:

M. A. Abu-Eid

Chemistry Department, An-Najah National University, Nablus, Palestine

Current Affiliation:

Department of Chemistry, Faculty of Science, An-Najah National University, Nablus, Palestine

[email protected]

P. J. Tait

UMIST, Chemistry Department, Sackville Street Manchester, U.K.

Preferred Abstract (Original):

The kinetics of the polymerization of 4-methylpentcne-1- with the MgC12|EB|Ticl4|Al(iBu)3 catalyst systems have been investigated. The conditions and requirements to achieve the highest activity and stereospecificity of the MgC12-supported catalyst systems were discussed. Moreover, the role of aluminum alkyl and ethyl benzoate on the activity and stereo-regularity of the polymers have been reported.

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Polymerization of 4-Methylpentene -1- by the MgCl2|Eb|TiCl4|Al(iBu)3 Catalyst System 1. Kinetic Investigations